I'm looking to toggle an npn transistor with 5v on the collector (emitter connected to an LED then ground). I've seen the options here but would it work to simply connect two DIOs to the base pin, providing a sum of 6.6V and causing the npn to open all the way when both DIOs are set to high?
The DIOs can not be operated in series like that. Here are a few options for driving the LEDs:
https://labjack.com/support/app-notes/driving-leds